Search results for "electric dipole moment"
showing 10 items of 88 documents
Ultracold Rare-Earth Magnetic Atoms with an Electric Dipole Moment
2018
We propose a new method to produce an electric and magnetic dipolar gas of ultracold dysprosium atoms. The pair of nearly degenerate energy levels of opposite parity, at 17513.33 cm$^{-1}$ with electronic angular momentum $J=10$, and at 17514.50 cm$^{-1}$ with $J=9$, can be mixed with an external electric field, thus inducing an electric dipole moment in the laboratory frame. For field amplitudes relevant to current-day experiments, we predict a magnetic dipole moment up to 13 Bohr magnetons, and an electric dipole moment up to 0.22 Debye, which is similar to the values obtained for alkali-metal diatomics. When a magnetic field is present, we show that the electric dipole moment is strongly…
Optical Shielding of Destructive Chemical Reactions between Ultracold Ground-State NaRb Molecules
2020
Polar quantum gases represent promising platforms for studying many-body physics and strongly correlated systems with possible applications e.g. in quantum simulation or quantum computation. Due to their large permanent electric dipole moment polar molecules in electric field exhibit strong long-range anisotropic dipole-dipole interactions (DDIs). The creation and trapping of ultracold dipolar diatomic molecules of various species are feasible in many experimental groups nowadays. However long time trapping is still a challenge even in the case of the so called nonreactive molecules which are supposed to be immune against inelastic collisions in their absolute ground state [1] . Various hyp…
Dipole Moments and the Direction of the Transition Dipole Moment of Some Intramolecular Exciplexes
1988
The dipole moments of some intramolecular exciplex systems have been determined from the effect of an electric field on their fluorescence and are compared to those estimated from solvent shift measurements. The charge transfer between the donor and acceptor subunits is between 0.6 and 0.9 of a full charge transfer. The face-to-face type exciplexes show considerable deviations from the general behaviour what might be due to some admixture of locally excited configurations to the exciplex wave function, in this way reducing the dipole moment values and changing the direction of the transition dipole moment.
Studies of rotational level Λ-doubling by rf-optical double resonance spectroscopy: application to NaK D1Π
1997
Abstract We report here the application of optical-radio frequency double resonance spectroscopy for individual rotational levels of the NaK D 1 Π state. Lambda doubling constant q values for five ν′, J ′ levels are obtained. These data are combined with measurements of dc e - f Stark-mixing-induced changes in optical spectra, and the electric dipole moment d p in the D 1 Π state is determined.
Theoretical absorption spectrum of the Ar–CO van der Waals complex
2003
The three-dimensional intermolecular electric dipole moment surface of Ar–CO is calculated at the coupled cluster singles and doubles level of theory with the aug-cc-pVTZ basis set extended with a 3s3p2d1f1g set of midbond functions. Using the rovibrational energies and wave functions of our recent study [J. Chem. Phys. 117, 6562 (2002)], temperature-dependent spectral intensities are evaluated and compared to available experimental data. Based on the theoretical spectrum, alternative assignments of the experimentally observed lines in the fundamental band of CO around 2160 and 2166 cm−1 are suggested. Thomas.Bondo@uv.es
Experimental constraints on the coupling of the Higgs boson to electrons
2015
In the standard model (SM), the coupling of the Higgs boson to electrons is real and very small, proportional to the electron mass. New physics could significantly modify both real and imaginary parts of this coupling. We discuss experiments which are sensitive to the Higgs-electron coupling and derive the current bounds on new physics contributing to this coupling. The strongest constraint follows from the ACME bound on the electron electric dipole moment (EDM). We calculate the full analytic two-loop result for the electron EDM and show that it bounds the imaginary part of the Higgs-electron coupling to be less than 1.7 x 10^-2 times the SM electron Yukawa coupling. Deviations of the real…
Experimental and theoretical studies of Λ doublings and permanent electric dipoles in the low-lying Π1 states of NaCs
2006
We present experimental data on the electric permanent dipole moments d(v',J') and lambda splittings (q factors) in the quasidegenerate (3) 1pi(e/f) state of the NaCs molecule over a wide range of the vibrational (v') and rotational (J') quantum numbers by using the combination of dc Stark mixing and electric radio frequency-optical double resonance methods. Within the experimental (3) 1pi state v' ranged from v' = 0 to 34, q values exhibited a pronounced decrease from 7.91x10(-6) to 0.47x10(-6) cm(-1), while absolute value(d) values varied between 8.0 and 5.0 D. Experimental evaluation yielded small d values about 1 D for D2 1pi state v'3 levels. The experiment is supported by ab initio el…
Stark level crossing and optical-rf double resonance in NaK D 1 Π
1997
We report here (Lambda) -doubling splitting and permanent electric dipole moment d p measurements for a number of vibrotational levels of NaK D 1 II state. Two different methods, which are not Doppler limited, were used. Stark effect induced level crossing was registered as fluorescence polarization changes with external electric field, which allowed us to obtain, from one fit, the values of electric dipole moment and (Lambda) -doubling splitting (Delta) ef between e, f substates of an individual rotational state. Another method consisted in obtaining the ratio (Delta) ef /d p from electric field dependence of the intensity of forbidden line appeared in fluorescence as a result of e- f Star…
The behavior of the 180° domain walls in disordered dielectrics like KTaO3 : Li and KTaO3 : Nb
2003
We calculate the structure of 180° domain wall in disordered ferroelectrics with random site electric dipoles (i.e. those like K 1-x Li x TaO 3 , KTa 1-x Nb x O 3 , where Li + or Nb 5+ are off-center ions forming impurity dipoles). The calculation is performed on the base of the free energy functional of disordered dielectrics derived earlier [M. D. Glinchuk et al., Phase Transit., 2003 (to be published)] within the framework of a random field method. We obtain the domain wall thickness as a function of impurity dipole concentration n and temperature T. It is shown that in disordered ferroelectrics the domain wall is usually broader than in their ordered counterparts. The thickness increase…
New constraints on Lorentz invariance violation from the neutron electric dipole moment
2010
We propose an original test of Lorentz invariance in the interaction between a particle spin and an electromagnetic field and report on a first measurement using ultracold neutrons. We used a high sensitivity neutron electric dipole moment (nEDM) spectrometer and searched for a direction dependence of a nEDM signal leading to a modulation of its magnitude at periods of 12 and 24 hours. We constrain such a modulation to $d_{12} < 15 \times 10^{-25} \ e\,{\rm cm}$ and $d_{24} < 10 \times 10^{-25} \ e\,{\rm cm}$ at 95~\% C.L. The result translates into a limit on the energy scale for this type of Lorentz violation effect at the level of ${\cal E}_{LV} > 10^{10}$~GeV.